Perovskite Study Correlates Phase Transition and Photoluminescence

Three research teams at Clemson University joined forces to study the phase transition in nanocrystal (NC) perovskites and the correlation between phase transition and photoluminescence (PL). The researchers studied NCs that included chlorine (CsPbCl₃), bromine (CsPbBr₃), and iodine (CsPbI₃). The researchers discovered that when exposed to heat, the chlorine-based NCs behaved differently than the iodide- or bromine-based ones.

The investigation of the temperature-dependent PL and time-resolved photoluminescence (TRPL) of NCs in the 80 to 300 K temperature range revealed a correlation between phase transition, electronic structure, and exciton dynamics. However, in contrast to the CsPbBr₃ and CsPbI₃ NCs, which exhibited a continuous blueshift in their bandgap with increasing temperature, the CsPbCl₃ NCs exhibited a blueshift until about 193 K, followed by a redshift until they reached room temperature. The researchers attributed the change from a blueshift to a redshift to a structural phase transition in CsPbCl₃, which also manifested in the temperature-dependent TRPL.

Jun Yi, a student in Clemson University's department of physics and astronomy, worked with professor Apparao Rao, researcher Exian Liu, and professor Jianbo Gao to study the correlation between the phase transition of nanocrystal perovskites and their emission properties. Courtesy of College of Science/Clemson University.

The study as a whole presents comprehensive temperature-dependent spectroscopic signatures of all-inorganic perovskite CsPbasX₃ NCs, which could provide further insight into the effect of phase transition on the low temperature photophysics of perovskite materials. The researchers said that the study has relevance to many applications that are broadly used in daily living, such as LEDs, lasers, solar cells, and photodetectors.

The low-temperature phase transition of CsPbCl₃ at about 193 K resulted in a reverse temperature dependence of bandgap that redshifted with increasing temperature until 300 K. The researchers estimated that the pronounced phase transition in CsPbCl₃ NCs was due to the condensation of their vibrational modes at low temperature, as well as the presence of the weak quantum confinement effect. The exciton recombination lifetimes showed a similar reverse trend due to the phase transition in CsPbCl₃.

The research was published in Nanoscale Advances (www.doi.org/10.1039/D0NA00545B).