In the study, conducted at the University of Michigan, a blue PHOLED consisting of a thin film of light-emitting material was sandwiched between two conductive layers: one for electrons and one for holes.
Light was produced when electrons and holes met on the light-emitting molecules. However, damaging energy transfers occurred from electron-hole pairs that tended to accumulate near the electron-conducting layer.
To control this effect, the researchers arranged the molecules so they were concentrated instead near the hole-conducting layer. This drew electrons further into the material, spreading out the light-producing energy and reducing the damage. The new distribution was found to extend the lifetime of blue PHOLEDs by three times.
Next, the team split the design into two layers, halving the concentration of light-emitting molecules in each layer. This time, the new configuration increased the lifetime tenfold.
Previous experiments conducted by the team found that the high energies required to produce blue PHOLEDs can actually be more damaging when the brightness is increased to levels needed for displays or lighting.
“That early work showed why the blue PHOLED lifetime is short, but it didn’t provide a viable strategy for increasing the lifetime,” said Yifan Zhang, a UM researcher.