Jean-Pierre Wolf and his team at the University of Lyon I -- working with the city's Department of Urban Ecology -- analyzed the particles with a differential absorption lidar system based on a Ti:sapphire-pumped optical parametric oscillator. The system is similar to that used in the team's previous work (see Photonics Spectra, April 1994, pp. 97-100) but extends into the mid-IR. The researchers also supplemented their lidar system with new inversion algorithms invoking fractal models, and scanning electron microscopy and electron-excited x-ray microanalysis.
Earlier work was essentially qualitative, measuring overall particle density, but the new mappings show the number of particles of specific sizes and shapes at any location over the city. The rhinopharyngeal system filters out particles larger than about 1 µm; smaller particles are deposited in the lungs, where their effects are noxious.
To obtain 3-D profiles of individual particles and their distribution in space, the researchers needed to know their light-scattering properties. Without this information, the data obtained from lidar measurements could not be broken down for use in identifying individual particle types. Somewhat accurate information was already available for such smooth particles as the products of soil erosion, but was not for more complex particles such as those found in soot from vehicle exhaust.
These latter particles, Wolf said, have a fractal-type surface, making analysis difficult.